100m3 new vertical liquid nitrogen storage tank

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I have an ethanol storage tank with nitrogen blanketing and I would like to determine the vapor composition in the tank. However I am a bit stuck on the calculation. Tank volume = 100m3. Tank level = 50% Tank head space = 50m3 Liquid = ethanol (100% assumption but in real life 96%) Tank temperature = 293 K Vapor pressure ethanol = 7343 Pa

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